Air Toxics Monitoring
in New Jersey
NJDEP measures outdoor air concentrations
of air toxics at four monitoring sites in New Jersey.
They are located in Camden, Elizabeth, New Brunswick,
and Chester. The Camden site has been measuring several
toxic volatile organic compounds (VOCs) since 1989. The
Elizabeth site began measuring VOCs in 2000, and the
New Brunswick and Chester sites became operational in
July 2001. Also in July 2001, analysis for toxic
metals began at all four sites. Air toxics monitoring
data summaries can be found in the annual NJDEP Air
Quality Report. Some results are discussed
below.
NJDEP Air Toxics Monitoring
Sites

COMPARISON OF
THE 1999 NATA RESULTS TO THE MONITORED CONCENTRATION OF AIR
TOXICS IN NEW JERSEY
Twenty-three of the compounds measured
at the Camden monitoring site in 1999 had enough data
to compare to the 1999 NATA modeled concentrations. The
Camden monitoring site is located at Copewood and Davis
Streets, in census tract 6015. The monitoring data
was compared with the modeled concentrations predicted
by 1999 NATA for that census tract. The comparisons
are shown in the graph and table below. It appears
from this analysis that the agreement between the predicted
and monitored concentrations is remarkably good for most
of the chemicals. Modeling predictions are dependent
on many variables, any of which can vary from the
actual conditions, and many of which can not be accounted
for. The results produced by the modeling depend
on emission estimates for stationary, area, and mobile
sources, meteorological conditions, and how well the
dispersion model represents what happens in reality.
Monitored Concentrations
of Air Toxics at Camden in 1999
Compared to 1999 NATA Predicted Concentrations

Monitored Concentrations
of Air Toxics at Camden in 1999
Compared to 1999 NATA Predicted Concentrations
Pollutant |
1999
Monitored Concentration
ug/m3 |
1999
Predicted Concentration
ug/m3 |
Acetaldehyde |
3.24 |
2.56 |
Acetonitrile |
0.86 |
0.012 |
Acrylonitrile |
0.56 |
0.0011 |
Benzene |
1.82 |
1.87 |
Bromomethane |
0.08 |
0.35 |
1,3-Butadiene |
0.22 |
0.17 |
Carbon
tetrachloride |
0.50 |
0.28 |
Chloroform |
0.002 |
0.14 |
1,4-Dichlorobenzene |
0.24 |
0.11 |
Ethyl
chloride |
0.02 |
0.03 |
Ethylbenzene |
0.87 |
0.74 |
Formaldehyde |
5.03 |
2.54 |
Methyl
chloride |
1.73 |
1.23 |
Methyl
isobutyl ketone |
0.08 |
0.38 |
Methyl
tert-butyl ether |
3.57 |
2.09 |
Methylene
chloride |
0.59 |
0.95 |
Perchloroethylene |
1.02 |
0.29 |
Styrene |
0.34 |
0.056 |
Toluene |
4.44 |
4.63 |
1,2,4-Trichlorobenzene |
0.02 |
0.0001 |
1,1,1-Trichloroethane |
0.33 |
1.73 |
Trichloroethylene |
0.11 |
0.18 |
Xylenes |
9.63 |
2.93 |
TRENDS IN MONITORED AIR TOXICS CONCENTRATIONS
The graphs below show the ambient air
concentrations for five air toxics that have been monitored
in New Jersey over the years. Benzene, 1,3-butadiene,
and formaldehyde are pollutants of concern in New Jersey,
meaning that their air concentrations exceed their health
benchmarks. Monitored levels of toluene and
xylene have consistently been below their health benchmarks.
Benzene

Benzene is emitted from many different
types of sources, but primarily from mobile sources. It
is a major component of gasoline. It is widely
used as a solvent, and as a starting material in the
production of numerous other chemicals. It ranks
in the top 20 in production volume for chemicals produced
in the U.S., although its use in consumer products (glues,
paints, furniture wax, detergents) has been decreasing
significantly. It is a known human carcinogen.
1,3-Butadiene

1,3-butadiene primarily comes from on-road
mobile sources (cars, trucks), so it is not surprising
to see higher levels at the Elizabeth monitoring site,
which is located next to the New Jersey Turnpike. Other
it also used in the production of rubber and plastics. Although
the overall trend in the air concentration from 1994
has been downward, levels measured at every site except
Chester (in rural Morris County) still tend to be above
the health benchmark. 1,3-butadiene is classified
as probably causing cancer in humans.
Formaldehyde

Formaldehyde air concentrations are
affected by direct emissions, and by formation from the
interaction of other pollutants. Formaldehyde is emitted during
the production and use of household goods (such as cosmetics,
cleaning products, and manufactured wood products) and
industrial chemicals, and sources of combustion (such
as cigarette smoke, gas cookers, fireplaces, and of course,
automobile exhaust). The graph shows that
formaldehyde concentrations haven’t changed much
in the recent past, and aren’t even very different
in urban and rural areas. Levels are above the
health benchmark. Formaldehyde is classified as
a probable human carcinogen. There is no data point for 2003 because of a monitoring instrument malfunction.
Toluene and Xylene
Toluene and xylene, presented in the
graphs below, are components of gasoline, and are emitted
mostly from mobile sources. They are also used
in large quantities as solvents and in the production
of other chemicals. These chemicals are used in
the manufacture of paints, coatings, insecticides, pharmaceuticals,
adhesives, and many other products. Fortunately,
NJDEP’s air monitors show them to be at levels
below their health benchmarks. They are not known
to cause cancer.


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